INKJET PRINTER

 Inkjet printing is a type of computer printing that recreates a digital image by propelling droplets of ink onto paper, plastic, or other substrates. Inkjet printers are the most commonly used type of printer, and range from small inexpensive consumer models to very large professional machines that can cost tens of thousands of dollars, or more. The concept of inkjet printing originated in the 19th century, and the technology was first extensively developed in the early 1950s. Starting in the late 1970s inkjet printers that could reproduce digital images generated by computers were developed, mainly by Epson, Hewlett-Packard (HP), and Canon. In the worldwide consumer market, four manufacturers account for the majority of inkjet printer sales: Canon, HP, Epson, and Lexmark, a 1991 spin-off from IBM.The emerging ink jet material deposition market also uses inkjet technologies, typically printheads using piezoelectric crystals, to deposit materials directly on substrates.

There are two main technologies in use in contemporary inkjet printers: continuous (CIJ) and Drop-on-demand (DOD).

Another emerging printing technology is EHD. Liquids can be printed at nanoscale by pyro-EHD.

Drop-on-demand

Most consumer inkjet printers, including those from Canon, Hewlett-Packard, and Lexmark, use the thermal inkjet process. The idea of using thermal excitation to move tiny drop of ink was developed independently by two groups at roughly the same time: John Vaught and a team at Hewlett-Packard's Corvallis Division, and Canon engineer IchiroEndo. Initially, in 1977, Endo's team was trying to use the piezoelectric effect to move ink out of the nozzle but noticed that ink shot out of a syringe when it was accidentally heated with a soldering iron. Vaught's work started in late 1978 with a project to develop fast, low-cost printing. The team at HP found that thin-film resistors could produce enough heat to fire an ink droplet. Two years later the HP and Canon teams found out about each other's work. In the thermal inkjet process, the print cartridges consist of a series of tiny chambers, each containing a heater, all of which are constructed by photo lithography. To eject a droplet from each chamber, a pulse of current is passed through the heating element causing a rapid vaporization of the ink in the chamber and forming a bubble, which causes a large pressure increase, propelling a droplet of ink onto the paper (hence Canon's trade name of Bubble Jet). The ink's surface tension, as well as the condensation and resultant contraction of the vapor bubble, pulls a further charge of ink into the chamber through a narrow channel attached to an ink reservoir. The inks involved are usually water-based and use either pigments or dyes as the colorant. The inks must have a volatile component to form the vapor bubble; otherwise droplet ejection cannot occur. As no special materials are required, the print head is generally cheaper to produce than in other inkjet technologies.

Most commercial and industrial inkjet printers and some consumer printers (those produced by Epson and Brother Industries) use a piezoelectric material in an ink-filled chamber behind each nozzle instead of a heating element. When a voltage is applied, the piezoelectric material changes shape, generating a pressure pulse in the fluid, which forces a droplet of ink from the nozzle. Piezoelectric (also called Piezo) inkjet allows a wider variety of inks than thermal inkjet as there is no requirement for a volatile component, and no issue with kogation (buildup of ink residue), but the print heads are more expensive to manufacture due to the use of piezoelectric material (usually PZT, lead zirconium titanate). A DOD process uses software that directs the heads to apply between zero to eight droplets of ink per dot, only where needed. Piezo inkjet technology is often used on production lines to mark products. For instance, the "use-before" date is often applied to products with this technique; in this application the head is stationary and the product moves past. Requirements of this application are high speed, a long service life, a relatively large gap between the print head and the substrate, and low operating cost.

Ink formulations

The basic problem with inkjet inks is the conflicting requirements for a coloring agent that will stay on the surface vs. rapid dispersement of the carrier fluid.

Desktop inkjet printers, as used in offices or at home, tend to use aqueous inks based on a mixture of water, glycol and dyes or pigments. These inks are inexpensive to manufacture, but are difficult to control on the surface of media, often requiring specially coated media. HP inks contain sulfonated polyazo black dye (commonly used for dying leather), nitrates and other compounds. Aqueous inks are mainly used in printers with thermal inkjet heads, as these heads require water to perform.

While aqueous inks often provide the broadest color gamut and most vivid color, most are not waterproof without specialized coating or lamination after printing. Most Dye-based inks, while usually the least expensive, are subject to rapid fading when exposed to light. Pigment-based aqueous inks are typically more costly but provide much better long-term durability and ultraviolet resistance. Inks marketed as "Archival Quality" are usually pigment-based.

Some professional wide format printers use aqueous inks, but the majority in professional use today employ a much wider range of inks, most of which require piezo inkjet heads and extensive maintenance:

Solvent inks

the main ingredient of these inks are volatile organic compounds (VOCs), organic chemical compounds that have high vapor pressures. Color is achieved with pigments rather than dyes for excellent fade-resistance. The chief advantage of solvent inks is that they are comparatively inexpensive and enable printing on flexible, uncoated vinyl substrates, which are used to produce vehicle graphics, billboards, banners and adhesive decals. Disadvantages include the vapour produced by the solvent and the need to dispose of used solvent. Unlike most aqueous inks, prints made using solvent-based inks are generally waterproof and ultraviolet-resistant (for outdoor use) without special over-coatings. The high print speed of many solvent printers demands special drying equipment, usually a combination of heaters and blowers. The substrate is usually heated immediately before and after the print heads apply ink. Solvent inks are divided into two sub-categories: hard solvent ink offers the greatest durability without specialized over-coatings but requires specialized ventilation of the printing area to avoid exposure to hazardous fumes, while Mild or "Eco" solvent inks, while still not as safe as aqueous inks, are intended for use in enclosed spaces without specialized ventilation of the printing area. Mild solvent inks have rapidly gained popularity in recent years as their color quality and durability have increased while ink cost has dropped significantly.

UV-curable inks

these inks consist mainly of acrylic monomers with an initiator package. After printing, the ink is cured by exposure to strong UV-light. Ink is exposed to UV radiation where a chemical reaction takes place where the photo-initiators cause the ink components to cross-link into a solid. Typically a shuttered mercury-vapor lamp is on either side of the print head, and produces a great amount of heat to complete the curing process (this lamp is used for free radical UV ink, which is what the majority of flatbed inkjet systems use). UV inks do not evaporate, but rather cure or set as a result from this chemical reaction. No material is evaporated or removed, which means about 100% of the delivered volume is used to provide coloration. This reaction happens very quickly, which leads to instant drying that results in a completely cured graphic in a matter of seconds. This also allows for a very fast print process. As a result of this instant chemical reaction no solvents penetrate the substrate once it comes off the printer, which allows for high quality prints. The advantage of UV-curable inks is that they "dry" as soon as they are cured, they can be applied to a wide range of uncoated substrates, and they produce a very robust image. Disadvantages are that they are expensive, require expensive curing modules in the printer, and the cured ink has a significant volume and so gives a slight relief on the surface. Though improvements are being made in the technology, UV-curable inks, because of their volume, are somewhat susceptible to cracking if applied to a flexible substrate. As such, they are often used in large "flatbed" printers, which print directly to rigid substrates such as plastic, wood or aluminium where flexibility is not a concern.

Dye sublimation inks

these inks contain special sublimation dyes and are used to print directly or indirectly on to fabrics which consist of a high percentage of polyester fibres. A heating step causes the dyes to sublimate into the fibers and create an image with strong color and good durability.